%mem=3000MB
%nprocshared=4
#p opt=maxstep=6 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm guess=always scf=qc empiricaldispersion=gd3 int=ultrafine

ch3och3-nh2_6311+Gd

-1 1
 C                 -1.22800600   -0.11678900    0.13310400
 H                 -1.32599700   -1.07859100   -0.36152200
 H                 -0.71642300    0.59977800   -0.50234000
 H                 -0.72486900   -0.22025700    1.09004000
 N                  1.97543500   -1.29789100   -0.52503500
 H                  1.12930300   -1.42142100   -1.09042900
 H                  1.64555000   -0.73471200    0.26539000
 O                 -2.54468099    0.38184506    0.38336597
 C                 -3.24012251    0.53671491   -0.85650355
 H                 -4.22567867    0.90857260   -0.66861818
 H                 -2.71068423    1.22789239   -1.47849133
 H                 -3.30436975   -0.41043872   -1.35013529

