%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3och3-och3_6311+Gd_new

-1 1
 C	-0.936900000	-0.395490000	 0.004262000
 H	-0.629381000	 0.161721000	 0.897083000
 H	-0.477263000	-1.383602000	 0.019718000
 H	-0.599826000	 0.147061000	-0.887024000
 O	-2.350744000	-0.584010000	-0.017027000
 C	-3.055934000	 0.653289000	-0.038407000
 H	-4.121598000	 0.421924000	-0.053663000
 H	-2.828651000	 1.251738000	 0.852830000
 H	-2.800115000	 1.237325000	-0.931498000
 O	 2.438036000	 0.046995000	 0.285907000
 C	 3.771921000	 0.039358000	-0.151443000
 H	 4.467817000	-0.432511000	 0.573055000
 H	 3.916674000	-0.512610000	-1.103363000
 H	 4.178836000	 1.055716000	-0.333601000




