%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3f-och2ch3_6311+Gd

-1 1
 C                 -1.74829900    0.16098000    0.06314500
 H                 -1.49178000   -0.67222900   -0.58929100
 H                 -1.37520600    1.10159400   -0.33942200
 H                 -1.37756700   -0.00525300    1.07355900
 C                  2.81913600    0.15643300   -0.06118000
 H                  3.46965400   -0.59343600    0.43842900
 H                  3.33084500    0.38023900   -1.02202800
 O                  1.52126200   -0.33586600   -0.26625600
 C                  2.85946000    1.43427800    0.78658500
 H                  2.42202300    1.25409800    1.77549900
 H                  3.88590300    1.79606700    0.93000300
 H                  2.28228400    2.23301400    0.30638200
 O                 -3.17440997    0.24495106    0.12683469
 H                 -3.42730572    0.97469984    0.69701927

