%mem=40000MB
%nprocshared=20
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3cl-cf3_6311+Gd_aq

-1 1
 C                 -1.56006600    0.16157500   -0.10044300
 H                 -1.37014500    1.31116400   -0.14134500
 H                 -1.22314900   -0.30578000    0.89910400
 H                 -1.08961100   -0.37905700   -1.01976700
 C                  1.87291400   -0.08072100   -0.48995500
 F                  1.59106700    1.10378500    0.27425800
 F                  1.61605700   -1.08374500    0.49507000
 F                  3.30777500   -0.05592300   -0.45717200
 Cl                -3.37565800   -0.11062000   -0.15566700

