%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3cl-sch3_6311+Gd_new

-1 1
 C	 1.483905000	 0.144998000	 0.057249000
 H	 1.109266000	-0.300012000	 0.973904000
 H	 1.246882000	 1.204078000	 0.014322000
 H	 1.096514000	-0.375165000	-0.813529000
 S	-2.028720000	-0.083924000	-0.068358000
 C	-3.869461000	 0.122659000	 0.030958000
 H	-4.380214000	-0.406545000	-0.781527000
 H	-4.269824000	-0.267142000	 0.973717000
 H	-4.161636000	 1.176842000	-0.034344000
 Cl	 3.305171000	-0.024581000	 0.051191000




