%mem=4000MB
%nprocshared=4
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
guess=always scf=qc empiricaldispersion=gd3 int=ultrafine

ch3f-nch33_6311+Gd

0 1
 C                 -1.23612200   -0.12718500    0.14079600
 H                 -1.35032900   -1.08396600   -0.36684600
 H                 -0.70338300    0.58725600   -0.48455600
 H                 -0.74030500   -0.25253300    1.10234800
 F                 -2.53495800    0.39282500    0.38544600
 N                  1.96317800   -1.28620600   -0.52341600
 C                  2.43479677   -0.56315298    0.66640334
 H                  3.25561520   -0.34551293    1.31739483
 H                  2.04680728    0.34935951    0.26430246
 H                  1.66675541   -1.06552454    1.21652633
 C                  1.74717371   -2.01505393   -1.78159836
 H                  1.97040814   -2.63993426   -2.62099753
 H                  1.00178919   -2.48548563   -1.17497168
 H                  1.38183811   -1.07059993   -2.12719427
 C                  2.09639027   -2.36988735    0.46085491
 H                  2.64351121   -1.68079973   -0.14801037
 H                  2.60225936   -2.50026554    1.39466324
 H                  2.02645464   -3.31204488   -0.04148781

