%mem=3000MB
%nprocshared=4
#p opt=maxstep=3 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm guess=always
scf=qc empiricaldispersion=gd3 int=superfinegrid

ch3f-nhcho_6311+Gd

-1 1
 C                 -1.35837800   -0.11737800    0.13262100
 H                 -0.85153800   -1.06890200   -0.03237800
 H                 -1.11624200    0.59800000   -0.65419500
 H                 -1.11453300    0.28833600    1.11461700
 F                 -2.75589000   -0.35470400    0.09078500
 N                  2.20873400    0.65979200    0.23972500
 H                  2.60163800    0.30799500   -0.63294100
 C                  2.87561500    0.12904100    1.23099800
 O                  2.66062900    0.34134800    2.47690000
 H                  3.70308600   -0.57317400    0.99728700

