%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3f-sch3_6311+Gd_new

-1 1
 C	-1.466325000	 0.103060000	-0.009547000
 H	-1.023152000	-0.733629000	-0.547068000
 H	-1.263021000	 1.043989000	-0.519105000
 H	-1.114405000	 0.134836000	 1.020331000
 F	-2.874779000	-0.086463000	 0.013738000
 S	 2.069444000	-0.025606000	 0.110613000
 C	 3.858945000	 0.440588000	-0.033705000
 H	 4.422883000	 0.161682000	 0.863634000
 H	 4.338448000	-0.055543000	-0.885242000
 H	 3.985373000	 1.520188000	-0.173548000




