%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3f-cn_6311+Gd_new

-1 1
 C	-1.296054000	 0.022015000	 0.000397000
 H	-0.909334000	-0.273103000	 0.975002000
 H	-0.859654000	-0.586361000	-0.790802000
 H	-1.121356000	 1.081489000	-0.182560000
 F	-2.699183000	-0.197894000	-0.000087000
 C	 2.123522000	 0.358310000	 0.009414000
 N	 3.012926000	-0.403617000	-0.021011000




