%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sh_new

0 1
 C	 1.168270000	-0.019199000	 0.000009000
 H	 1.531305000	-0.527068000	-0.893450000
 H	 1.541089000	 1.005431000	-0.000072000
 H	 1.531279000	-0.526918000	 0.893564000
 H	-0.912289000	-1.241088000	 0.000068000
 S	-0.666957000	 0.088935000	-0.000026000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


