%mem=16000MB
%nprocshared=12
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3ph2_6311+Gd

0 1 
 P                 -1.15909100    2.86363600    0.00000000
 H                  0.19090710    2.86363490   -0.00226702
 H                 -1.83408910    1.69450280    0.00226702
 C                 -2.06909100    4.43980224    0.00000000
 H                 -1.49007384    5.18594077    0.50290796
 H                 -2.24891860    4.74782155   -1.00880431
 H                 -3.00328037    4.31229116    0.50589638

