%mem=3000MB
%nprocshared=4
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3oTf_6311+Gd_water 

0 1
 C                  1.13517400    0.35825300   -0.00206200
 S                 -0.43739700   -0.69505700    0.05104300
 O                 -0.81515200   -0.81386700    1.44730500
 O                 -0.18704000   -1.84771300   -0.78667000
 O                 -1.44710000    0.25132400   -0.75017100
 C                 -2.24981800    1.25379300   -0.02883900
 H                 -2.85648600    0.76322100    0.72925700
 H                 -1.59919700    2.00968100    0.40731100
 H                 -2.87569000    1.68654700   -0.80459000
 F                  2.11518500   -0.30674600    0.60569100
 F                  1.47547500    0.60162700   -1.26396000
 F                  0.92177600    1.51303200    0.63082800

