%mem=3000MB
%nprocshared=4
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3nhcho_6311+Gd

0 1
 N                 -0.45909848    0.14190317    0.00000000
 H                 -0.21888432    0.48451682   -0.90824724
 C                  0.03091000    0.83486143    1.20025020
 O                 -0.27137348    0.40371500    2.34318852
 H                  0.64461027    1.70585743    1.10207716
 C                 -1.30222177   -1.05469715    0.13487324
 H                 -1.56102940   -1.42003725   -0.83695247
 H                 -0.76554448   -1.81080562    0.66889334
 H                 -2.19379320   -0.80424298    0.67085188



