%mem=3000MB
%nprocshared=4 
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3nh2_6311+Gd

0 1
 N                 -4.75708496    2.14556508    0.02808688
 H                 -4.42227121    1.20328120    0.02717229
 H                 -4.42523937    2.61801959   -0.78840883
 C                 -4.26707648    2.83852334    1.22833708
 H                 -4.62532720    3.84676710    1.22931569
 H                 -4.62215126    2.33299612    2.10198697
 H                 -3.19707825    2.84020478    1.22735970

