%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3oooch_6311+Gd 

0 1
 8 -0.135037 -0.964360 0.072157
 8 0.866143 -0.182277 -0.652859
 6 -1.296738 -0.243891 0.200875
 1 -2.019309 -0.924860 0.674208
 8 -1.491677 0.903810 -0.122257
 6 1.692786 0.428559 0.345130
 1 2.458939 0.938117 -0.243550
 1 1.122654 1.153597 0.931514
 1 2.145989 -0.332245 0.985468




