%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3f_new

0 1
 C	-0.000000000	-0.000000000	-0.664088000
 H	 0.000000000	 1.036712000	-1.002018000
 H	 0.897819000	-0.518356000	-1.002018000
 H	-0.897819000	-0.518356000	-1.002018000
 F	-0.000000000	-0.000000000	 0.749282000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


