%mem=3000MB
%nprocshared=4 
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm pop=full volume

ts_6311+Gd

-1 1
 C                 -2.82729792    0.20891365    0.00000000
 C                 -1.43213792    0.20891365    0.00000000
 C                 -0.73459992    1.41666465    0.00000000
 C                 -1.43225392    2.62517365   -0.00119900
 C                 -2.82707892    2.62509565   -0.00167800
 C                 -3.52467992    1.41688965   -0.00068200
 H                 -3.37705692   -0.74340335    0.00045000
 H                 -0.88262992   -0.74359935    0.00131500
 H                 -0.88205392    3.57731665   -0.00125800
 H                 -3.37720092    3.57737665   -0.00263100
 C                 -5.06467988    1.41714594   -0.00093409
 H                 -5.42128570    2.28569012    0.51225524
 H                 -5.42117938    1.42744816   -1.00974625
 H                 -5.42157408    0.53847756    0.49451360
 S                  1.04539978    1.41679414    0.00102623
 O                  1.53453215    2.13919884    1.18365260
 O                  1.53591965    2.07958533   -1.21545322
 O                  1.53548064    0.03132816    0.03573602

