%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

sch3_6311+Gd_new

-1 1
 S	-0.000000000	-0.000000000	 0.168099000
 C	-0.000000000	-0.000000000	-1.687234000
 H	 0.151115000	 1.007587000	-2.091590000
 H	 0.797039000	-0.634663000	-2.091590000
 H	-0.948154000	-0.372924000	-2.091590000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


