%mem=3000MB
%nprocshared=4 
#p opt=maxstep=4 freq=noraman rb3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3

sch2ch3_6311+Gd

-1 1
 S                 -0.11519497    0.68127803   -0.04755284
 C                  0.00003900   -0.00004800   -1.68795400
 C                  0.79822100   -1.31626000   -1.64222500
 H                  0.67795200   -1.77314700   -0.68217800
 H                  0.43679000   -1.97909200   -2.40046100
 H                  1.83450100   -1.11105200   -1.81226300
 H                 -0.98302574   -0.19196899   -2.06431825
 H                  0.49779256    0.69682284   -2.32944635

