%mem=3000MB
%nprocshared=4 
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

nch33_6311+Gd_new

0 1
 N                  0.07617782   -0.30821212   -0.01721434
 C                  0.56616100   -1.69414736   -0.01721434
 H                  0.20789246   -2.19910969    0.85545782
 H                  0.21108564   -2.19798078   -0.89184191
 H                  1.63615921   -1.69416118   -0.01525894
 C                  0.56399081    0.38396994    1.18437730
 H                  0.20733782    1.39278046    1.18437642
 H                  0.20572024   -0.12099248    2.05704857
 H                  1.63398902    0.38395485    1.18633445
 C                  0.56837933    0.38552146   -1.21611859
 H                  0.21330457   -0.11831265   -2.09074599
 H                  0.21172491    1.39433146   -1.21611859
 H                  1.63837754    0.38550789   -1.21416259

