%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

cn_6311+Gd_new

-1 1
 6	-0.646376000	 1.246851000	 0.000000000
 7	 0.533530000	 1.246851000	 0.000000000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


