%mem=10000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

sch3_6311+Gd

-1 1
 S                  0.00000000    0.00000000    0.07982400
 C                  0.00000000    0.00000000   -1.70017600
 H                  0.14962410    0.99764811   -2.05684235
 H                  0.78917639   -0.62840253   -2.05684235
 H                 -0.93880054   -0.36924560   -2.05684286

