%mem=40000MB
%nprocshared=24
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3Ts-cl_6311+Gd_ch2cl2

-1 1
 C                  2.25365900   -0.86117300   -0.97905100
 C                  0.89400100   -1.15254600   -0.94978300
 C                  0.10537500   -0.67820900    0.10110800
 C                  0.68089500    0.08141400    1.11425600
 C                  2.04749800    0.36695800    1.07574200
 C                  2.85474300   -0.09730300    0.03324900
 H                  2.86056500   -1.23121600   -1.80100200
 H                  0.44745200   -1.74268400   -1.74295000
 H                  0.06280500    0.45101300    1.92368300
 H                  2.48734100    0.96348100    1.86995800
 C                  4.33459800    0.18958500   -0.00184000
 H                  4.60902000    0.97970100    0.70100900
 H                  4.91268700   -0.70307900    0.26231200
 H                  4.65867000    0.49636100   -1.00067800
 S                 -1.67619000   -1.02479700    0.09992700
 O                 -2.19593600   -0.44940400    1.37236000
 O                 -1.79543800   -2.50856700    0.02171800
 O                 -2.20305500   -0.33373900   -1.11364300
 C                 -1.45153000    2.52801500   -0.51902700
 H                 -2.24759800    2.61737200   -1.25679100
 H                 -0.59126400    2.00795200   -0.93419100
 H                 -1.80885700    2.03379400    0.38137700
 Cl                -0.93915894    4.15426011   -0.08267539

