%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3cl-sh_6311+Gd

-1 1
 C                  0.73527900   -0.06669700    0.00141400
 H                  0.41093900   -0.29483600    1.01235300
 H                  0.34837800    0.89565400   -0.31976800
 H                  0.43830100   -0.85246500   -0.68707500
 Cl                 2.55907500    0.02535700   -0.00062400
 H                 -6.98993011   -0.10964283   -0.00583100
 S                 -5.63180311   -0.10052483    0.00015300

