%mem=16000MB
%nprocshared=12
#p opt=(calcfc,maxstep=2) freq b3lyp/genecp       
scrf=(smd,solvent=dichloromethane) nosymm scf=qc empiricaldispersion=gd3

ch3f-c6h5_6311+Gd

-1 1
 C                 -1.33168300   -0.24448200    0.31237500
 H                 -0.68344000   -0.01070700    1.15510100
 H                 -0.85125900   -0.94592600   -0.36804900
 H                 -1.63000400    0.66227300   -0.21214900
 Br                -2.50730600   -0.86244500    0.82151900
 C                  2.06671900    0.80027600   -0.47585100
 C                  2.38007500   -0.27097200    0.39790700
 C                  3.13811600    1.71630100   -0.63015600
 C                  3.61247500   -0.42752000    1.05070000
 H                  1.62794600   -1.04036000    0.59368900
 C                  4.38274000    1.59364500    0.00712900
 H                  3.01093900    2.58440400   -1.28301300
 C                  4.62784300    0.51280300    0.85799200
 H                  3.78206700   -1.27885300    1.70965800
 H                  5.16123000    2.33821600   -0.15786600
 H                  5.58705400    0.40572600    1.35854600

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
Br     0
S   2   1.00
      1.1590000             -3.0378769
      0.7107000              3.3703735
S   1   1.00
      0.1905000              1.0000000
P   2   1.00
      2.6910000             -0.1189800
      0.4446000              1.0424471
P   1   1.00
      0.1377000              1.0000000
P   1   1.00
      0.0376                 1.0
D   1   1.00
      0.4340                 1.0
****

BR     0
BR-ECP     3     28
f potential
  4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
  4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
  5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
  5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270



