%mem=3000MB
%nprocshared=4
#p opt=maxstep=10 freq=noraman b3lyp/genecp scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3cl-nhcho_6311+Gd_ch2cl2__

-1 1
 N	-1.322005000	 0.850489000	-0.161081000
 H	-1.448770000	 1.834649000	 0.078756000
 C	-2.441654000	 0.209770000	 0.115464000
 O	-2.673409000	-1.019185000	-0.043291000
 H	-3.284165000	 0.817622000	 0.539220000
 C	 2.103492000	 0.026481000	-0.040439000
 H	 1.620241000	 0.054266000	 0.954325000
 H	 1.898527000	 0.996817000	-0.531013000
 H	 1.588396000	-0.753841000	-0.630879000
 Br	 3.812579000	-0.281627000	 0.082570000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si -As -Se 0
6-311+g*
****
Br     0
S   2   1.00
1.1590000             -3.0378769
0.7107000              3.3703735
S   1   1.00
0.1905000              1.0000000
P   2   1.00
2.6910000             -0.1189800
0.4446000              1.0424471
P   1   1.00
0.1377000              1.0000000
P   1   1.00
0.0376                 1.0
D   1   1.00
0.4340                 1.0
****

BR     0
BR-ECP     3     28
f potential
4
1    213.6143969            -28.0000000
2     41.0585380           -134.9268852
2      8.7086530            -41.9271913
2      2.6074661             -5.9336420
s-f potential
4
0     54.1980682              3.0000000
1     32.9053558             27.3430642
2     13.6744890            118.8028847
2      3.0341152             43.4354876
p-f potential
5
0     54.2563340              5.0000000
1     26.0095593             25.0504252
2     28.2012995             92.6157463
2      9.4341061             95.8249016
2      2.5321764             26.2684983
d-f potential
5
0     87.6328721              3.0000000
1     61.7373377             22.5533557
2     32.4385104            178.1241988
2      8.7537199             76.9924162
2      1.6633189              9.4818270

