%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-oTs_6311+Gd_ch2cl2

-1 1
 C                  3.53143135    0.21200280   -1.30939709
 H                  3.18288303    0.30940898   -2.33907996
 H                  3.13870366   -0.71581511   -0.88864047
 H                  3.16866155    1.05688835   -0.72394960
 S                  5.35638191    0.11508888   -1.24740931
 C                 -4.25751200   -0.79487000   -0.18318000
 C                 -2.90767000   -1.14881100   -0.25761100
 C                 -1.92854400   -0.18612000   -0.03760500
 C                 -2.29621400    1.12938600    0.25741000
 C                 -3.64217400    1.47066900    0.32820300
 C                 -4.64684300    0.51480200    0.10930800
 H                 -5.01537800   -1.55372900   -0.35616600
 H                 -2.61563400   -2.16738200   -0.48495100
 H                 -1.53437400    1.88202500    0.43114400
 H                 -3.92130300    2.49562100    0.55761200
 C                 -6.10090200    0.90471700    0.19603400
 H                 -6.35901700    1.24443400    1.20473700
 H                 -6.33167400    1.72896300   -0.48654600
 H                 -6.75815400    0.06838500   -0.05280900
 S                 -0.16711600   -0.61223400   -0.14829600
 O                  0.42178300   -0.19680800    1.15808300
 O                  0.35721100    0.17979900   -1.29839100
 O                 -0.12235400   -2.08359900   -0.37532000
 H                  5.86988715    1.13033785   -1.89677970

