%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-nch33_6311+Gd_ch2cl2

0 1
 C                 -0.69023600   -0.61881700    0.27684100
 H                 -0.10835600   -1.50675900    0.02633800
 H                 -0.24601600    0.24162200   -0.22546100
 H                 -0.66342000   -0.47048700    1.35794300
 N                  2.94183511    0.51913521    1.21578497
 C                  3.07860334    0.70310200    2.65583873
 H                  4.10795313    0.98050603    2.95112008
 H                  2.40524866    1.49225592    2.99891402
 H                  2.81462841   -0.21942064    3.17865374
 C                  3.22446592    1.75683756    0.49861088
 H                  4.26159584    2.10981027    0.65183915
 H                  3.07229046    1.61131801   -0.57404486
 H                  2.54639014    2.54627380    0.83356021
 C                  3.78748612   -0.57054460    0.74271326
 H                  4.86361113   -0.37755709    0.91134099
 H                  3.52598545   -1.49792382    1.25908330
 H                  3.63584637   -0.72423273   -0.32888395
 S                 -2.40251100   -0.89649600   -0.29610900
 H                 -2.38134159   -1.46774821   -1.47480437

