%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-c6h5_6311+Gd_ch2cl2

-1 1
 C                  2.52705902   -3.94509180   -1.72537294
 H                  1.86247836   -4.08736780   -0.87219002
 H                  3.51641179   -3.63247378   -1.38255542
 H                  2.10971795   -3.16410813   -2.36316002
 C                  2.37192100   -1.18955400   -0.62783600
 C                  2.23950000    0.03364400   -1.33205900
 C                  1.89332700    1.25667500   -0.73802500
 C                  1.65126000    1.32029200    0.63589700
 C                  1.76809200    0.14930000    1.38891300
 C                  2.11904100   -1.05497400    0.76054900
 H                  2.40904800    0.05022700   -2.41225700
 H                  1.80304300    2.15755400   -1.34448400
 H                  1.37138000    2.25889000    1.10809300
 H                  1.57947200    0.17612500    2.46217700
 H                  2.19115500   -1.93566800    1.40533900
 S                  2.62681335   -5.47280818   -2.71857373
 H                  3.88391588   -5.78175865   -2.91942898

