%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3shsh

-1 1
 C                  0.84860100    0.24554700   -0.00697200
 H                  0.38361400   -0.19273900    0.87898200
 H                  0.68570700    1.32669500    0.00510700
 H                  0.39766500   -0.17072300   -0.91065600
 H                  2.64726200   -1.36878800   -0.01426400
 S                  2.67237100   -0.01806000    0.00382300
 H                 -4.33414400   -0.04370400    0.00348600
 S                 -2.97685300   -0.04594200    0.00112600

