%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3shoh

-1 1
 C                 -0.15596300   -0.26848900    0.00557300
 H                  0.30494600    0.13695600    0.90946200
 H                 -0.01366700   -1.35267800   -0.00905000
 H                  0.31913900    0.16268100   -0.87883200
 H                 -1.92554500    1.37835800    0.01721300
 S                 -1.97417300    0.02841300   -0.00430500
 O                  3.65248800    0.08407700    0.01024000
 H                  4.61776800    0.15839300   -0.08528200

