%mem=16000MB
%nprocshared=12
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3shcl

-1 1
 C                  0.91357200    0.18572400    0.00616000
 H                  0.47878300   -0.25388600    0.90715100
 H                  0.70182800    1.25858100   -0.00127100
 H                  0.46788800   -0.26838500   -0.88220800
 H                  2.78427500   -1.34529000    0.00900500
 S                  2.74692000    0.00517900   -0.00317100
 Cl                -3.16852500   -0.03460200   -0.00111200

