%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-sch2ch3_6311+Gd_ch2cl2

-1 1
 C                 -1.08503000    0.71159900   -0.06724300
 H                 -0.78200600    0.11148200   -0.92631500
 H                 -0.61298300    1.69227100   -0.14080900
 H                 -0.74797600    0.22867000    0.85113400
 S                 -2.89541300    0.96022000   -0.04869100
 C                 -3.42510500   -0.79847500    0.07377600
 H                 -3.02538252   -1.22994194    0.96762063
 H                 -3.06420992   -1.33965123   -0.77580215
 S                  2.63704200   -0.24715100   -0.11565500
 C                  4.43624400   -0.70148200   -0.13124400
 H                  4.59870100   -1.55969600    0.53241100
 H                  4.71693700   -1.03597600   -1.13757700
 C                  5.37289900    0.43077400    0.29050400
 H                  5.14661000    0.76839000    1.30745800
 H                  6.42547800    0.11264400    0.26641500
 H                  5.26780700    1.29612700   -0.37256300
 H                 -4.49361451   -0.84810142    0.10069542

