%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-och2ch3_6311+Gd_ch2cl2

-1 1
 C                 -0.61425800   -1.13694000   -0.03194900
 H                 -0.38837700   -2.20415100   -0.06083900
 H                 -0.17204500   -0.66201000   -0.90938100
 H                 -0.17364700   -0.71074900    0.87092900
 C                  4.35172100   -0.13612600    0.15818200
 H                  4.75545600   -0.21488300    1.20760500
 H                  5.21996000   -0.47090500   -0.47801400
 O                  3.22075000   -0.86099800   -0.04322600
 C                  4.19720600    1.37844900   -0.11483800
 H                  3.42247000    1.80343000    0.53579500
 H                  5.13260000    1.93339400    0.05581900
 H                  3.88382600    1.54504100   -1.15317600
 S                 -2.43156000   -0.94934700   -0.02783300
 C                 -2.53152400    0.88764700    0.02804400
 H                 -2.04625948    1.24451314    0.91238834
 H                 -2.04821481    1.29753103   -0.83410871
 H                 -3.55821126    1.18882361    0.03833618

