%mem=3000MB
%nprocshared=4
#p opt=(maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3och2ch3-sh_6311+Gd_ch2cl2

-1 1
 C	 0.766921000	 0.435757000	 0.050484000
 H	 0.477934000	-0.026343000	 1.001438000
 H	 0.311616000	 1.423258000	-0.021554000
 H	 0.403320000	-0.190229000	-0.772633000
 O	 2.180242000	 0.612036000	-0.025561000
 C	 2.890588000	-0.627895000	 0.057488000
 H	 2.641011000	-1.126265000	 1.004570000
 H	 2.565237000	-1.287497000	-0.759031000
 C	 4.376463000	-0.351407000	-0.031806000
 H	 4.705140000	 0.295299000	 0.786826000
 H	 4.936109000	-1.289016000	 0.030090000
 H	 4.629058000	 0.133388000	-0.979215000
 H	-4.174751000	-0.208885000	 0.418169000
 S	-2.826444000	-0.078946000	 0.335559000




