%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3nch33-cf3_6311+Gd_ch2cl2

0 1
 N                  2.21325000    0.00040800   -0.03976500
 C                  0.72439300   -0.08443000   -0.25079700
 H                  0.51695800   -0.07051900   -1.31770000
 H                  0.35911500   -1.00829500    0.18916100
 H                  0.25246900    0.76817900    0.23021500
 C                  2.73146400    1.27248600   -0.64636300
 H                  3.80656100    1.32776000   -0.48449400
 H                  2.51119400    1.26704200   -1.71228600
 H                  2.23583600    2.11543900   -0.16887900
 C                  2.50876800   -0.01221500    1.43236200
 H                  2.12848600   -0.93903200    1.85736300
 H                  3.58584500    0.05257600    1.57698900
 H                  2.01538700    0.83937200    1.89672100
 C                  2.87889800   -1.17531400   -0.69479800
 H                  2.65472700   -1.15569300   -1.75969800
 H                  3.95359700   -1.10595100   -0.53561200
 H                  2.49151800   -2.08981700   -0.24975300
 C                 -2.59472900    0.00078100   -0.41664700
 F                 -2.56903300    1.18877000    0.39154900
 F                 -2.25793100   -0.97966200    0.58014400
 F                 -4.00605800   -0.21041400   -0.50349500

