%mem=3000MB
%nprocshared=4
#p opt=(maxstep=4,calcfc) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3nch33-cl_6311+Gd_ch2cl2

0 1
 N                 -1.39642400   -0.01816000    0.01841900
 C                  0.10409800   -0.14755200    0.15195700
 H                  0.35907400   -0.27992900    1.19981000
 H                  0.42884000   -1.01905300   -0.41937600
 H                  0.57411400    0.75050200   -0.24152800
 C                 -1.87078900    1.17168000    0.80815500
 H                 -2.95304500    1.25800300    0.70125400
 H                 -1.60223200    1.02286800    1.85624300
 H                 -1.38230300    2.06635300    0.41131000
 C                 -1.76008500    0.17148400   -1.42988500
 H                 -1.42814300   -0.70281300   -1.98946300
 H                 -2.84848800    0.28193300   -1.51449700
 H                 -1.26064000    1.06999300   -1.80485700
 C                 -2.05585300   -1.26732300    0.54764900
 H                 -1.78273000   -1.38957300    1.59850200
 H                 -3.14361200   -1.16385200    0.45376100
 H                 -1.70479500   -2.11682000   -0.02950400
 Cl                 3.53239500    0.03598600   -0.04210900

