%mem=3000MB
%nprocshared=4
#p opt=(maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3nch33-sch2ch3_6311+Gd_ch2cl2

0 1
 N	 0.010892000	-0.240988000	 0.016072000
 C	 0.252931000	-1.714522000	 0.193446000
 H	-0.299391000	-2.055023000	 1.066018000
 H	-0.092078000	-2.234446000	-0.696552000
 H	 1.318330000	-1.878043000	 0.335185000
 C	 0.484815000	 0.495121000	 1.235808000
 H	 0.304308000	 1.558918000	 1.093895000
 H	-0.068194000	 0.131448000	 2.099686000
 H	 1.548934000	 0.307297000	 1.364646000
 C	 0.764139000	 0.247833000	-1.187197000
 H	 0.411897000	-0.293890000	-2.062839000
 H	 0.580395000	 1.314014000	-1.305224000
 H	 1.825367000	 0.063107000	-1.032828000
 C	-1.457665000	 0.004551000	-0.178043000
 H	-1.989948000	-0.352449000	 0.701347000
 H	-1.619325000	 1.072965000	-0.308396000
 H	-1.787591000	-0.536818000	-1.062593000
 S	 1.003310000	-5.126787000	 0.180211000
 C	 1.311129000	-6.952750000	 0.304117000
 H	 2.294900000	-7.123142000	 0.756466000
 H	 1.360133000	-7.379623000	-0.704249000
 C	 0.258786000	-7.711365000	 1.111266000
 H	 0.484563000	-8.785792000	 1.153269000
 H	 0.207548000	-7.339143000	 2.139663000
 H	-0.736185000	-7.594978000	 0.669371000




