%mem=3000MB
%nprocshared=4
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3c6h5-nch33_6311+Gd_ch2cl2

0 1
 C                  1.16842667    1.95754698   -0.18874000
 H                  0.63768667    2.46405398   -0.99932300
 H                  1.10582467    0.88087598   -0.36248200
 H                  0.61939367    2.17917198    0.73185200
 C                  2.59940367    2.42427998   -0.09230700
 C                  3.65940267    1.51569198    0.00727800
 C                  2.89890567    3.79424998   -0.08607900
 C                  4.98004267    1.95874498    0.11265800
 H                  3.45069367    0.44938898    0.00180700
 C                  4.21488167    4.24205998    0.01879500
 H                  2.08958467    4.51539398   -0.16502900
 C                  5.26320967    3.32413798    0.11914700
 H                  5.78638367    1.23529898    0.18784300
 H                  4.42355167    5.30773598    0.02055900
 H                  6.28869167    3.67098198    0.19930500
 N                 -3.38571100    0.18152000    0.06092400
 C                 -4.03262500    0.88931200   -1.03747900
 H                 -4.04249800    1.96381700   -0.83658100
 H                 -3.48064400    0.72247900   -1.96624300
 H                 -5.07719400    0.56224200   -1.19781600
 C                 -3.30290700   -1.24849300   -0.21177600
 H                 -2.75112100   -1.42259200   -1.13869800
 H                 -2.77300100   -1.75510300    0.59850900
 H                 -4.29933200   -1.71789700   -0.31420500
 C                 -4.06333800    0.43707000    1.32647600
 H                 -3.53362700   -0.06270500    2.14177700
 H                 -4.07380100    1.50999800    1.53565400
 H                 -5.10980000    0.07832200    1.32876500

