%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3Ts-och3_6311+Gd_ch2cl2

-1 1
 C                  2.81830800    0.63839100   -0.83283000
 C                  2.03024600   -0.50425000   -0.76049200
 C                  0.97875500   -0.53834200    0.15607000
 C                  0.70498800    0.54478200    0.98928300
 C                  1.50525600    1.68019400    0.89828200
 C                  2.57034000    1.74549500   -0.00810200
 H                  3.63946800    0.67180000   -1.54220500
 H                  2.22971900   -1.35481900   -1.40150700
 H                 -0.11789100    0.50664800    1.69255300
 H                  1.29241600    2.52894200    1.54012800
 C                  3.44979300    2.96531000   -0.08241700
 H                  2.94746400    3.84858700    0.31767600
 H                  4.36568700    2.81427600    0.50004600
 H                  3.75260300    3.17724700   -1.11101400
 S                 -0.07304200   -1.97812400    0.21970300
 O                 -0.70916800   -2.03981000    1.53602300
 O                  0.65234200   -3.13803500   -0.28893700
 O                 -1.20551700   -1.69587000   -0.90462800
 C                 -2.16309800   -0.60442300   -0.66288900
 H                 -2.67130200   -0.75710100    0.28579100
 H                 -1.65919900    0.35780600   -0.68239000
 H                 -2.86641000   -0.67360000   -1.48633900
 O                 -3.54839900    1.92133500   -0.40755600
 C                 -4.61295500    2.64799300    0.02834100
 H                 -5.57173000    2.46178400   -0.53018300
 H                 -4.89312400    2.47243700    1.10407100
 H                 -4.48290100    3.76412600   -0.03254800

