%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3Ts-f_6311+Gd_ch2cl2

-1 1
 C	-2.875010000	 0.503967000	-1.108053000
 C	-1.521788000	 0.462371000	-1.416088000
 C	-0.632068000	 1.182777000	-0.616314000
 C	-1.068232000	 1.929030000	 0.477046000
 C	-2.429538000	 1.955893000	 0.765126000
 C	-3.350060000	 1.249128000	-0.017935000
 H	-3.575745000	-0.050250000	-1.723787000
 H	-1.167686000	-0.115826000	-2.261117000
 H	-0.364398000	 2.477191000	 1.090785000
 H	-2.778530000	 2.534331000	 1.613857000
 C	-4.822845000	 1.302857000	 0.281007000
 H	-5.013782000	 1.626320000	 1.305945000
 H	-5.321263000	 2.011638000	-0.389113000
 H	-5.294838000	 0.329324000	 0.128123000
 S	 1.106750000	 1.084386000	-0.964975000
 O	 1.800194000	 2.188631000	-0.296730000
 O	 1.327601000	 0.866441000	-2.393378000
 O	 1.583421000	-0.317564000	-0.292401000
 C	 1.509749000	-0.436968000	 1.164651000
 H	 2.097968000	 0.348170000	 1.636410000
 H	 0.470008000	-0.400529000	 1.487867000
 H	 1.937447000	-1.412594000	 1.377502000
 F	 1.181450000	-0.838241000	 4.447768000




