%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3Ts-c6h5_6311+Gd_ch2cl2

-1 1
 C	 2.927524000	 0.667403000	-4.570481000
 C	 2.703219000	 0.984102000	-3.232956000
 C	 1.398760000	 0.932670000	-2.745938000
 C	 0.322948000	 0.569680000	-3.559011000
 C	 0.572366000	 0.257843000	-4.889704000
 C	 1.872938000	 0.300977000	-5.415252000
 H	 3.938836000	 0.708543000	-4.960566000
 H	 3.526694000	 1.269208000	-2.589661000
 H	-0.685639000	 0.537000000	-3.165212000
 H	-0.255769000	-0.021491000	-5.532955000
 C	 2.113417000	-0.036435000	-6.861114000
 H	 1.756909000	-1.045388000	-7.089044000
 H	 1.566568000	 0.649731000	-7.515013000
 H	 3.172446000	 0.018768000	-7.118103000
 S	 1.099184000	 1.314751000	-1.041083000
 O	-0.292489000	 1.783127000	-0.850382000
 O	 2.185104000	 2.164264000	-0.500183000
 O	 1.238765000	-0.178472000	-0.409564000
 C	 1.018019000	-0.300576000	 1.037244000
 H	 1.743416000	 0.305588000	 1.577890000
 H	-0.002383000	-0.012773000	 1.284774000
 H	 1.177546000	-1.354379000	 1.244763000
 C	 0.757980000	-0.818777000	 4.719934000
 C	 2.076434000	-1.252263000	 5.007155000
 C	 0.012401000	-0.493305000	 5.881127000
 C	 2.607309000	-1.357917000	 6.301947000
 H	 2.741240000	-1.528386000	 4.184606000
 C	 0.511402000	-0.587144000	 7.189691000
 H	-1.018105000	-0.144381000	 5.778247000
 C	 1.820823000	-1.023207000	 7.407122000
 H	 3.630447000	-1.699619000	 6.450751000
 H	-0.116798000	-0.320887000	 8.038345000
 H	 2.219274000	-1.100548000	 8.415080000




