%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3oTs-nch33_6311+Gd_ch2cl2

0 1
 C	 2.740722000	 0.800120000	-4.189293000
 C	 2.822540000	 0.332741000	-2.882872000
 C	 1.664355000	 0.321200000	-2.106014000
 C	 0.437722000	 0.757271000	-2.605827000
 C	 0.381285000	 1.220325000	-3.915352000
 C	 1.525798000	 1.250883000	-4.724149000
 H	 3.635253000	 0.814661000	-4.802899000
 H	 3.766771000	-0.011597000	-2.478950000
 H	-0.452355000	 0.739906000	-1.988813000
 H	-0.567261000	 1.563269000	-4.314751000
 C	 1.458327000	 1.785130000	-6.128136000
 H	 0.469826000	 1.634274000	-6.566921000
 H	 1.657237000	 2.862455000	-6.133354000
 H	 2.203392000	 1.313531000	-6.772330000
 S	 1.746721000	-0.300245000	-0.448857000
 O	 0.650335000	 0.239980000	 0.361315000
 O	 3.108980000	-0.176767000	 0.081144000
 O	 1.445235000	-1.873979000	-0.747047000
 C	 1.430865000	-2.767466000	 0.411462000
 H	 2.413421000	-2.786631000	 0.881456000
 H	 0.661001000	-2.456527000	 1.116690000
 H	 1.191538000	-3.742923000	-0.003722000
 N	 1.286130000	-0.693906000	 4.536941000
 C	-0.006438000	-0.584806000	 3.855856000
 H	-0.078219000	-1.331776000	 3.063071000
 H	-0.818993000	-0.760290000	 4.564419000
 H	-0.157966000	 0.409571000	 3.402805000
 C	 2.368328000	-0.475598000	 3.573971000
 H	 3.336488000	-0.561628000	 4.072329000
 H	 2.323931000	-1.226683000	 2.785010000
 H	 2.314353000	 0.520072000	 3.103173000
 C	 1.365917000	 0.309299000	 5.600593000
 H	 0.568081000	 0.150480000	 6.329382000
 H	 2.322968000	 0.230713000	 6.120934000
 H	 1.272639000	 1.338559000	 5.212407000




