%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3oTs-c6h5_6311+Gd_ch2cl2

-1 1
 C	 3.051847000	 0.566266000	-4.077486000
 C	 2.607862000	 0.923230000	-2.809247000
 C	 1.236284000	 0.916794000	-2.557832000
 C	 0.309391000	 0.560862000	-3.537431000
 C	 0.777873000	 0.208694000	-4.797636000
 C	 2.149520000	 0.206097000	-5.087662000
 H	 4.116684000	 0.567464000	-4.284819000
 H	 3.314465000	 1.201173000	-2.036817000
 H	-0.752579000	 0.560326000	-3.324345000
 H	 0.066678000	-0.069329000	-5.568238000
 C	 2.638737000	-0.147927000	-6.464843000
 H	 1.990632000	-0.886940000	-6.940923000
 H	 2.644156000	 0.740813000	-7.105371000
 H	 3.657656000	-0.539504000	-6.440311000
 S	 0.655891000	 1.333255000	-0.936112000
 O	-0.738569000	 1.787987000	-0.987159000
 O	 1.622895000	 2.195930000	-0.247795000
 O	 0.698618000	-0.144050000	-0.256611000
 C	 0.233527000	-0.242021000	 1.131644000
 H	 0.835196000	 0.397812000	 1.774575000
 H	-0.822313000	 0.019253000	 1.188331000
 H	 0.380657000	-1.285721000	 1.391745000
 C	 0.369090000	-1.075173000	 4.692448000
 C	 1.746999000	-1.013585000	 4.366510000
 C	 0.120217000	-0.958855000	 6.083484000
 C	 2.773979000	-0.855908000	 5.309664000
 H	 2.056095000	-1.090359000	 3.321353000
 C	 1.122071000	-0.797891000	 7.053181000
 H	-0.908752000	-0.993087000	 6.450032000
 C	 2.463667000	-0.745415000	 6.667408000
 H	 3.813777000	-0.817850000	 4.988548000
 H	 0.859194000	-0.713244000	 8.106461000
 H	 3.249341000	-0.621394000	 7.407712000




