%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3Ts-nch33_6311+Gd_ch2cl2

0 1
 C	 2.693531000	 1.200835000	-3.902153000
 C	 2.592924000	 0.788594000	-2.576238000
 C	 1.354737000	 0.355476000	-2.105418000
 C	 0.226479000	 0.320364000	-2.926511000
 C	 0.352159000	 0.735652000	-4.246871000
 C	 1.581515000	 1.182600000	-4.753718000
 H	 3.652482000	 1.540769000	-4.278728000
 H	 3.458931000	 0.806738000	-1.926109000
 H	-0.728756000	-0.020375000	-2.545542000
 H	-0.518033000	 0.712882000	-4.894548000
 C	 1.691558000	 1.659213000	-6.175798000
 H	 1.035302000	 1.090828000	-6.838733000
 H	 1.393088000	 2.710809000	-6.247657000
 H	 2.715327000	 1.582514000	-6.547139000
 S	 1.210559000	-0.191199000	-0.424954000
 O	-0.140196000	 0.096714000	 0.103993000
 O	 2.371025000	 0.271207000	 0.369927000
 O	 1.336808000	-1.797076000	-0.670870000
 C	 1.056070000	-2.682035000	 0.458932000
 H	 1.904285000	-2.696242000	 1.142537000
 H	 0.144435000	-2.374982000	 0.969718000
 H	 0.913774000	-3.659253000	 0.004908000
 N	 1.468780000	-0.729849000	 4.420819000
 C	 0.356777000	-0.191671000	 3.634918000
 H	 0.221756000	-0.776039000	 2.724403000
 H	-0.568829000	-0.240379000	 4.212704000
 H	 0.520796000	 0.860211000	 3.344074000
 C	 2.719161000	-0.571435000	 3.675562000
 H	 3.551632000	-0.988084000	 4.246770000
 H	 2.657370000	-1.100702000	 2.723982000
 H	 2.946586000	 0.486969000	 3.461390000
 C	 1.560621000	-0.022963000	 5.699701000
 H	 0.660818000	-0.198453000	 6.293509000
 H	 2.419738000	-0.385279000	 6.268219000
 H	 1.675717000	 1.067256000	 5.568596000




