%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-sh_6311+Gd_ch2cl2

-1 1
 C	 0.364287000	-0.486311000	 0.002562000
 H	 0.717664000	 0.042933000	 0.888426000
 H	 0.779212000	-1.494699000	 0.005195000
 H	 0.706460000	 0.033734000	-0.893116000
 S	-1.456556000	-0.630769000	 0.014604000
 H	 5.373933000	 0.294186000	-0.015787000
 C	-1.882743000	 1.159191000	 0.006363000
 H	-1.434923000	 1.610842000	-0.882696000
 H	-1.425344000	 1.621332000	 0.885096000
 S	 4.029222000	 0.109554000	-0.011534000
 C	-3.392174000	 1.362164000	 0.013315000
 H	-3.622665000	 2.431510000	 0.008185000
 H	-3.863360000	 0.915987000	-0.867106000
 H	-3.853795000	 0.926566000	 0.904041000




