%mem=40000MB
%nprocshared=20
#p opt freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3sch2ch3-c6h5_6311+Gd_ch2cl2

-1 1
 C	 2.312895000	-0.198294000	-3.059555000
 H	 1.239587000	-0.366171000	-2.955572000
 H	 2.599936000	-0.275395000	-4.110145000
 H	 2.846516000	-0.961442000	-2.490924000
 C	-0.630470000	 0.262172000	 0.164448000
 C	-0.550981000	 1.638703000	 0.494757000
 C	-0.905061000	 2.680796000	-0.375670000
 C	-1.375526000	 2.388723000	-1.657428000
 C	-1.479828000	 1.050548000	-2.042901000
 C	-1.112354000	 0.033419000	-1.149351000
 H	-0.189472000	 1.933989000	 1.482950000
 H	-0.810339000	 3.718117000	-0.058785000
 H	-1.642167000	 3.186572000	-2.344927000
 H	-1.835716000	 0.802430000	-3.041565000
 H	-1.209934000	-0.991774000	-1.515044000
 S	 2.773432000	 1.430251000	-2.375067000
 C	 1.777558000	 2.501746000	-3.491719000
 H	 2.179108000	 2.413397000	-4.504622000
 H	 0.756331000	 2.116341000	-3.494324000
 C	 1.802211000	 3.949420000	-3.020345000
 H	 2.818674000	 4.353638000	-3.005169000
 H	 1.207880000	 4.570565000	-3.697000000
 H	 1.379305000	 4.048436000	-2.017207000




