%mem=40000MB
%nprocshared=24
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=dichloromethane)
empiricaldispersion=gd3 scf=(maxcyc=1000,conver=8,nosym)

ch3Ts-f_6311+Gd_ch2cl2

-1 1
 C                  2.53760500   -0.49539100   -0.92241800
 C                  1.27152400   -1.06240500   -0.85256800
 C                  0.39686400   -0.63240600    0.14707300
 C                  0.76615100    0.34888100    1.06416300
 C                  2.04069900    0.90350700    0.97597000
 C                  2.94279000    0.49279800   -0.01193100
 H                  3.22443900   -0.82529500   -1.69572300
 H                  0.96892500   -1.82670800   -1.55867500
 H                  0.07435400    0.67522300    1.83107700
 H                  2.33271500    1.67023200    1.68610700
 C                  4.32814300    1.07661800   -0.09114300
 H                  4.41212000    1.99678100    0.49052900
 H                  5.06711200    0.36780800    0.29868700
 H                  4.60799500    1.29634300   -1.12501100
 S                 -1.24778800   -1.31915800    0.21138000
 O                 -1.81467800   -1.07100600    1.53598000
 O                 -1.24020200   -2.67037700   -0.33730400
 O                 -2.07995600   -0.45879800   -0.89100100
 C                 -2.55403378    2.82400323   -0.37435120
 H                 -3.48278865    2.26576289   -0.26731987
 H                 -2.24076406    2.86434203   -1.41727112
 H                 -1.77202496    2.37489785    0.23184949
 F                 -2.68827900    4.21851800   -0.24631600

