%mem=16000MB
%nprocshared=12
#p opt=(maxstep=5) freq b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm 

ch3f_cf3_6311+Gd

-1 1
 C                  2.16184600   -0.03234100    0.20731100
 H                  1.89689000    0.85425900    0.78333400
 H                  1.71332900   -0.00019600   -0.78386100
 H                  1.87484900   -0.93951600    0.73788400
 F                  3.57438000   -0.04574300    0.05082800
 C                 -1.18465500    0.06398200    0.35016800
 F                 -1.22159700    1.13844000   -0.60777800
 F                 -1.02295400   -1.05924700   -0.53487100
 F                 -2.59074100   -0.05104900    0.63868400

