%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym)

ch3shoh

-1 1
 C                  0.57519100   -0.01241200   -0.01212700
 H                  0.63822800    0.30192700    1.01567700
 H                  0.65291100   -1.05917200   -0.25695000
 H                  0.64264500    0.71654600   -0.80158000
 H                 -1.89153000    1.23161100    0.29431800
 S                 -1.74665600   -0.07831000   -0.01328400
 O                  2.68682300    0.08353000   -0.07445700
 H                  2.95851600   -0.53172100    0.62950800

